A Criterion for Flow-Induced Oriented Crystals in Isotactic Polypropylene under Pressure
نویسندگان
چکیده
منابع مشابه
Extensional-flow-induced crystallization of isotactic polypropylene
A filament stretching extensional rheometer with a custom-built oven was used to investigate the effect of uniaxial flow on the crystallization of polypropylene. Prior to stretching, samples were heated to a temperature well above the melt temperature to erase their thermal and mechanical histories and the Janeschitz-Kriegl protocol was applied. The samples were stretched at extension rates in ...
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Dispersions of isotactic polypropylene (PP) particles in polystyrene (PS) were produced by interfacially driven breakup of nanolayers in multilayered systems that were fabricated by means of layer-multiplying coextrusion. The droplet size was controlled by the individual PP layer thickness ranging from 12 to 200 nm. In addition, PP was melt blended with PS to produce PP droplets larger than tho...
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Nucleation of the γ-form in isotactic polypropylene (PP) under high pressure was investigated. Three nucleating agents were used to nucleate crystallization of PP under atmospheric pressure: commercial Hyperform HPN-20E from Milliken Chemical, poly(tetrafluoroethylene) particles nucleating the α-form, and calcium pimelate nucleating the β-form. Crystallization of neat PP and PP with addition of...
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Bulk isotactic polypropylene in the a form was studied using density functional theory-based computations. The computed physical structure of this system is in excellent agreement with available experimental data. The electronic band structure, ionization potential, and electron affinity were also determined. The impact of various types of chemical imperfections (including double bond, hydroxyl...
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BOITOUT, Hugo, "Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene random copolymer" (2014). Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene random copolymer Influence of the temperature on flow-induced crystallization of isotactic polypropylene and propylene-ethylene rando...
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ژورنال
عنوان ژورنال: Macromolecular Rapid Communications
سال: 2017
ISSN: 1022-1336
DOI: 10.1002/marc.201700407